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  1. Investigation of a thermocapacitive cycle by aqueous supercapacitors for multifunctional heat pump and energy storage

    Thermocapacitive cycles are promising thermal and energy storage cycles using supercapacitors, which can achieve thermal efficiencies over 50% of the Carnot limit. There is a lack of work investigating the use of thermocapacitive effects in practical heat pumps. Here, this paper explores the design of thermocapacitive cells with higher temperature changes to be better suited for heat pumping applications. To evaluate the cell designs on temperature changes, pouch type cells are prototyped and modeled, and tested using a micro-calorimeter. A peak adiabatic temperature span of a LiCl aqueous cell is 2.7 °C. By arranging the cells in a cascade manner,more » the projected adiabatic temperature span can reach up to 12 °C with a heating density of 15 kW m−3 and an energy storage density of 0.83 kWh m−3. Models predict that this could be increased to 30 °C and 1.65 kWh m−3 through improvements to cell capacitance and thermopower. Incorporating the energy storage capabilities into heating and cooling devices can be beneficial to building thermal management as energy storage becomes increasingly important for energy system integration.« less
  2. Defining Infrastructure Feasibility for Hub-Scale Offshore Atlantic Carbon Storage in the Northeastern United States

    In the Northeast U.S., deep rock formations along the Atlantic outer continental shelf may have the potential to sequester 150–1136 million metric tons of CO2. However, the design and infrastructure necessary to develop offshore carbon storage in this region is not well defined because there has been little oil and gas exploration and no commercial production. Consequently, an infrastructure feasibility design was completed for a hub-scale offshore CO2 storage system along the Northeast U.S. Atlantic. The design included development of a detailed, site-specific geological model for a location near the Great Stone Dome geological structure in the Baltimore Canyon Troughmore » off the coast of Delaware, Maryland, and New Jersey. A field injection system topology design was completed to portray a design with eight wells in two clusters connected by central manifolds. Reservoir simulations were completed for the injection system that showed the hub may be able to inject 17 million metric tons (MMT) of CO2 per year for thirty years, but injection rates varied substantially across the eight wells. A CO2 pipeline design determined feasible routes from the east coast shoreline to the injection field. Finally, the CO2 injection system design included subsea injection trees, manifolds, and power umbilicals. This is the first study to define large-scale carbon storage design and infrastructure options for the offshore Atlantic, which can help to progress this region towards field characterization and early-mover deployment for future decarbonization in the region.« less
  3. Unified Modeling Architecture for Load Management in Extreme Heat: The New York City Case

    Integration of renewable resources to meet growing energy demand is becoming a global priority under decarbonization mandates. This study contributes to ongoing efforts on this key subject by assessing the feasibility of using coastal-urban renewable energy resources, namely, offshore wind and rooftop photovoltaic systems, to meet electricity demand of New York City during the intense recent heat wave period of June 2025. A unified modeling framework, based on the urbanized weather research and forecasting model, is used to simulate climate, renewable resources, and energy demand variables. Findings show significant energy load mismatch of approximately 1150 GWh over the month, betweenmore » the demand and the combined renewable generation outcome. Three storage integration scenarios are analyzed to mitigate the deficits, reducing said deficits by a minimum of approximately 9% over the duration of the month. This study provides a transferable modeling framework tool for evaluating renewable integration in dense urban environments that can be used by grid operators to support grid resilience during extreme heat events.« less
  4. A path to intelligent watersheds: coordinating the data to decision pipeline

    Operations of multi-reservoir systems are challenged in-part by the interplay of complex physical processes functioning within the watershed. The employment of intelligent systems can be of aid by linking environmental sensing, information technology, data analytics, simulation and decision support to achieve a data-to-decision flow of information. A further challenge is that watershed resources are managed for multiple purposes requiring some level of coordination among numerous resource managers, asset operators and users. System intelligence in this context relies on shared community platforms (data portals, community models), and coordinated communication between decision makers. Opportunities to enrich watershed intelligence has been the subjectmore » of a roadmapping exercise for the Department of Energy’s Water Power Technologies Office which has relied on broad stakeholder engagement. Initial phases of engagement involved personal interviews and a series of virtual group meetings, which focused on identifying opportunities to improve the intelligence of the physical infrastructure within our watersheds—examples of feedback include improved sensing of snowpack and runoff, data standards for facilitated data sharing, and better forecasting tools. The latter phase of engagement involved the conduct of a case study in the Upper Colorado River basin where key stakeholders were interviewed to map how their decisions are informed by intelligence from other basin stakeholders. Our presentation will highlight the interdisciplinary flow of information in complex watershed systems and identify physical and institutional opportunities toward the strategic operation of water infrastructure.« less
  5. Energy Impact of Radiative Cooling Paints in Warehouses Under Various United States Climates

    Although radiative cooling research is widely found in the literature, no comprehensive study has yet been conducted on the impact of novel radiant cooling (>0.91 reflectance) on the energy efficiency of warehouses. Here, in this work, we develop three building models based on a Department of Energy prototype warehouse model using trnsys, representing a typical warehouse with a black roof, a typical warehouse with a white roof, and a warehouse with novel radiative cooling (RC) paint on its roof. These models are run for 15 different cities, each representative of a different ASHRAE climate zone, to better understand the impactmore » of RC in many different climates. It was found that an RC-coated roof in a warehouse could reduce the building's annual heating, ventilation, and air conditioning (HVAC) loads by up to 14.11 kWh/m2 of the roof area compared to a black roof, resulting in a maximum reduction in energy costs of 0.55 $$\$$$$/m2 or $$\$$$$2646/year for a large 4835 m2 warehouse. Similarly, replacing the typical white roof coating with an RC coating could reduce the warehouse's energy consumption by up to 8.17 kWh/ m2 of roof area, thus reducing energy costs by as much as 0.29 $$\$$$$/m2 or $$\$$$$1386/year for a 4835 m2 warehouse. In addition, applying RC paint to an unconditioned warehouse could reduce the building's ASHRAE Standard 55 indoor temperature exceedance by up to 1330 h/year compared to a black roof and up to 532 h/year compared to a white roof.« less
  6. Strengthening Resilience: Florida Resident Voices on Resource Needs During Power Outages

    Extreme weather events related to climate change, and an aging electricity infrastructure are disrupting reliable electricity services to a greater degree. Further, previous research has found that more socially vulnerable populations are more likely to live in areas with a higher probability of power outages. Here, this study examines the issues that people face during power outages and the resources that help individuals maintain resilience during power outages caused by extreme weather events in socially vulnerable communities. Using qualitative data from focus groups with 56 individuals in Central and North Florida, the research highlights lived experiences during outages and difficultiesmore » using and accessing resources during these conditions. Based on a qualitative review of the focus group discussions, this paper explores the solutions and support systems residents believe would improve their ability to cope. The findings offer insights to guide policy and strategic planning, with the goal of strengthening personal preparedness and response by focusing on the resources people consider most helpful for enduring frequent and severe outages.« less
  7. Evaluation of daily gridded climate products using in situ FLUXNET data and tree growth modeling

    Gridded climate data products have facilitated research in climate and ecology by providing meteorological data continuously across large spatial scales. However, the sensitivity of scientific outcomes to dataset choice remains poorly understood, and evaluation using station-based records can favor datasets built heavily on weather stations. Here, we evaluate seven high-resolution daily gridded datasets covering the contiguous United States using independent meteorology from the FLUXNET2015 dataset, with a focus on the implications of dataset choice for process-based tree growth modeling. We find that gridded products tend to capture temperature accurately while consistently overestimating the magnitude and frequency of precipitation and itsmore » extremes. Moreover, datasets vary in how they define a ‘day,’ which significantly affects temporal alignment with FLUXNET2015 observations. Despite differences among the datasets, the interannual variability in tree ring simulations is insensitive to dataset choice, likely because daily-scale biases are averaged out through accumulated growth across several months. However, inaccuracies in temperature and precipitation can significantly bias modeled xylem cell production, with systematically higher annual precipitation in the gridded datasets leading to greater xylem production compared to simulations using in situ data. Our results suggest that model applications, especially those that integrate to time scales longer than one day, are likely insensitive to climate dataset choice, but applications that are sensitive to daily climate variations or to absolute climate values need to carefully consider biases in gridded climate products.« less
  8. The levelized cost of exergy: a technoeconomic framework for energy system comparison

    While the levelized costs of electricity and heat have been quantified before, these two metrics cannot be directly compared, due to the different exergy content of heat and work. To address this, we develop a levelized cost of exergy (LCOEx) framework that enables direct comparisons between energy sources and processes. We find that moderate- and high-grade heat have an LCOEx that is comparable to electricity (5–10 ¢ per kWhex), while low-grade heat sources have much higher LCOEx values (>50 ¢ per kWhex). The LCOEx of a system's output is affected by (i) the LCOEx of the system input, (ii) themore » CAPEX of the system, and (iii) the exergetic efficiency of the system. We use our framework to identify which processes are already achieved with relatively high cost effectiveness (production of fuels, hydrogen, and ammonia) and which have room for improvement (dehumidification, food production).« less
  9. Compact Absorber Technology Leads to Significant Reduction in the Cost of Point Source CO2 Capture

    The size of columns in traditional absorption-based processes for CO2 capture contributes significantly to the overall capital cost. A demonstrated method to reduce the cost of point source CO2 capture, focusing on reducing the absorber height by increasing the liquid-to-gas reaction contact area and decreasing the CO2 diffusion resistance without increasing gas-side pressure drop is presented along with techno-economic analysis results. Bench-scale tests on the unique Compact Absorber showed overall CO2 mass transfer enhancement of varying degrees compared to a traditional packed column for similar process conditions, demonstrating that a 60+% reduction in size of a typical post-combustion absorber withmore » a packing height of 70-100 ft and total height of 150-180 ft can be achieved. The techno-economic analysis showed significant cost reductions when the Compact Absorber is combined with other transformative aspects of the University of Kentucky Institute for Decarbonization and Energy Advancement point source CO2 capture process compared to the U.S. Department of Energy National Energy Technology Laboratory pertinent reference case for pulverized coal plants with CO2 capture. Here, a levelized cost of electricity excluding CO2 transportation and storage of $$\$$95.6$/MWh was estimated, which is a 9% reduction, with a total capital cost contribution of $45/MWh, which is a 12% reduction. Additionally, a breakeven CO2 sales price also referred to as the cost of CO2 capture, of $36.70/tonne was estimated when the UK hindered primary amine solvent is used, which is a 20% reduction compared to the reference case.« less
  10. Decomposing sources of value for electricity and negative emissions technologies in net-zero power systems

    Deep decarbonization of the US power system would require rapid deployment of variable renewable energy (VRE) resources, which are projected to provide a substantial share of electricity generation at the time of net-zero emissions. However, the exact share of generation met by VRE and the roles of other technologies in supplying key electricity services—energy and firm capacity—remain uncertain. This study employs a detailed model of the US power sector to decompose the provision and value of electricity services, including negative emissions, by technology across a range of deep decarbonization scenarios. Results indicate that while technology deployment and the share ofmore » services provided by each technology vary significantly depending on future technological and market conditions, the value composition and future roles of individual technologies remain consistent. These findings offer guidance for research and development priorities and provide insights to inform electricity policy and planning.« less
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